Photoactive Earth-Abundant Iron Pyrite Catalysts for Electrocatalytic Nitrogen Reduction Reaction

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题名:	Photoactive Earth-Abundant Iron Pyrite Catalysts for Electrocatalytic Nitrogen Reduction Reaction
作者:	Chang, CC (Chang, Chia-Che) Li, SR (Li, Sin-Ren) Chou, HL (Chou, Hung-Lung) Lee, YC (Lee, Yi-Cheng) Patil, S (Patil, Shivaraj) Lin, YS (Lin, Ying-Sheng) Chang, CC (Chang, Chun-Chih) Chang, YJ (Chang, Yuan Jay) Wang, DY (Wang, Di-Yan)
贡献者:	化材系
关键词:	density functional theory earth-abundant electrocatalysts in situ XRD measurements iron pyrite nitrogen reduction reaction
日期:	2019-10
上传时间:	2019-12-13 13:14:55 (UTC+8)
摘要:	The generation of ammonia, hydrogen production, and nitrogen purification are considered as energy intensive processes accompanied with large amounts of CO2 emission. An electrochemical method assisted by photoenergy is widely utilized for the chemical energy conversion. In this work, earth-abundant iron pyrite (FeS2) nanocrystals grown on carbon fiber paper (FeS2/CFP) are found to be an electrochemical and photoactive catalyst for nitrogen reduction reaction under ambient temperature and pressure. The electrochemical results reveal that FeS2/CFP achieves a high Faradaic efficiency (FE) of approximate to 14.14% and NH3 yield rate of approximate to 0.096 mu g min(-1) at -0.6 V versus RHE electrode in 0.25 m LiClO4. During the electrochemical catalytic reaction, the crystal structure of FeS2/CFP remains in the cubic pyrite phase, as analyzed by in situ X-ray diffraction measurements. With near-infrared laser irradiation (808 nm), the NH3 yield rate of the FeS2/CFP catalyst can be slightly improved to 0.1 mu g min(-1) with high FE of 14.57%. Furthermore, density functional theory calculations demonstrate that the N-2 molecule has strong chemical adsorption energy on the iron atom of FeS2. Overall, iron pyrite-based materials have proven to be a potential electrocatalyst with photoactive behavior for ammonia production in practical applications.
關聯:	SMALL 文獻號碼: 1904723
显示于类别:	[化學工程與材料工程學系暨碩士班] 期刊論文

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