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    請使用永久網址來引用或連結此文件: https://irlib.pccu.edu.tw/handle/987654321/44612


    題名: Preparation of long-chain branched polyethylene terephthalates (PETs), and crystallization behaviors, thermal characteristics, and hydrolysis resistance of their biaxially stretching films
    作者: Chen, MH (Chen, Meng-Hsin)
    Lai, CC (Lai, Chiu-Chun)
    Chen, HL (Chen, Hsin-Lung)
    Lin, CH (Lin, Chen-Han)
    Hsiao, HT (Hsiao, Ho-Ting)
    Liu, LC (Liu, Lung-Chang)
    Chen, CM (Chen, Chien-Ming)
    貢獻者: 紡織工程學系
    關鍵詞: MELTING BEHAVIOR
    KINETICS
    POLY(ETHYLENE-TEREPHTHALATE)
    TEMPERATURE
    COMPOSITE
    FOAMS
    FABRICATION
    MORPHOLOGY
    STABILITY
    CONCRETE
    日期: 2019-06
    上傳時間: 2019-06-18 11:20:44 (UTC+8)
    摘要: Long-chain branched polyethylene terephthalates (PETs) composed of ethylene glycol, terephthalic acid, trimesic acid, and their biaxially stretching films with superior crystal sizes and inferior crystal growth rates, melting points, equilibrium melting points, fold surface free energies, and orientation parameters compared to common PET were manufactured by T-Die extrusion and biaxially stretching treatment. In order to evaluate the hydrolysis resistance for biaxially stretching films of lab-made long-chain branched PETs, we examined their half-life period of elongation, defined as the time for which the films could retain their elongation at 50% during the hydrolysis procedure under conditions of 100% humidity, 1.5 atm pressure and 120 degrees C. Experimental results revealed that biaxially stretching film of long-chain branched PET II had high potential as an optical substrate for optoelectronic devices because its half-life period of elongation was 58 compared to 21 h for common PET.
    顯示於類別:[紡織工程學系] 期刊論文

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