Analysis of the microstructure and physical properties of La0.85Sr0.15Ga0.8Mg0.2O2.825 and Ce0.85Sm0.15O1.925 composite electrolytes used in solid oxide fuel cells

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题名:	Analysis of the microstructure and physical properties of La0.85Sr0.15Ga0.8Mg0.2O2.825 and Ce0.85Sm0.15O1.925 composite electrolytes used in solid oxide fuel cells
作者:	Wu, Yu-Chuan Lee, Ming-Jin Li, Xiang
贡献者:	化材系
关键词:	Solid oxide fuel cell Conductivity mechanism Composite electrolyte Microstructure Sintering
日期:	2015-12
上传时间:	2016-02-26 10:43:35 (UTC+8)
摘要:	(100-x wt%) La0.85Sr0.15Ga0.8Mg0.2O2.825 (LSGM1520) + (x wt%) Ce0.85Sm0.15O1.925 (SDC15)(x=0, 2, 5, 7, 10, and 100) composite electrolytes were synthesized by a solid-state reaction. The microstructures and electrical properties of the electrolytes were analyzed by X-ray diffractometry, Raman spectroscopy, scanning electron microscopy, thermomechanical analysis, and impedance spectroscopy. The electrolytes, LSGM1520 and 95 wt% LSGM1520-5 wt% SDC15, based on a La0.6Sr0.4Co0.2Fe0.8O3-delta (LSCF6428) cathode and Ce0.8Sm0.2O1.9-Ni (SDC20-Ni) cathode were used to form two SOFCs. The thermal expansion coefficients of the composites ranged from 10.5 x 10(-6)/degrees C to 12 x 10(-6)/degrees C at 200-600 degrees C and 12 x 10(-6)/degrees C to 15 x 10(-6)/degrees C at 600-800 degrees C. The performances and current density of LSCF6428/LSGM1520/SDC20-Ni and LSCF6428/95L05S/SDC20-Ni are 264 mW/cm(2) and 1.00 A/cm(2) at 774 degrees C, and 182 mW/cm(2) and 0.97 A/cm(2) at 789 degrees C, respectively, and their open circuit voltages (OCV) are similar to 1.0-1.1 V. (C) 2015 Elsevier Ltd. All rights reserved.
關聯:	JOURNAL OF THE EUROPEAN CERAMIC SOCIETY 卷: 35 期: 16 頁碼: 4485-4495
显示于类别:	[化學工程與材料工程學系暨碩士班] 期刊論文

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