文化大學機構典藏 CCUR:Item 987654321/2918
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    题名: Sedimentation, rheology and particle-packing structure of aqueous Al2O3 suspensions
    作者: Tseng WJ
    Wu CH
    贡献者: 材料所
    关键词: grain growth
    Al2O3
    sedimentation
    rheology
    aggregation
    日期: 2003
    上传时间: 2009-11-30 11:46:46 (UTC+8)
    摘要: Gravity settling, rheology and particle-packing structure of aqueous alumina suspensions have been investigated using sub-micrometer alpha-Al2O3 powders with an average particle size similar to0.2 mum dispersed in pure water. The suspension pH varied from 2 to 11. The interface that separated the supernatant from the sediment appeared to settle linearly with time during the sedimentation experiment, followed then by a gradual reach toward a minimal sediment height; to which, the height was pH and solids loading dependent. The suspensions tended to form a continuous particulate network that defined the gravity settling as phigreater than or equal to0.1 at pH 11. This resulted in a flocculated suspension structure which barely settled even after 24 h without disturbance. The flocculated suspensions exhibited correspondingly a shear-thinning flow character over given shear-rate range (gamma = 1-1000 s(-1)) examined, in contrast to an apparent transition of flow toward shear thickening from the shear thinning for the better-dispersed suspensions (pH = 2) at relatively high shear rates (gamma greater than or equal to 100 s(-1)). This finding suggested a breakdown of the particulate network into smaller flow units for the flocculated suspensions as shear rate was increased. Films made from the flocculated suspensions showed apparent cracking after drying. Microstructural examinations revealed that a pronounced grain growth occurred in the films made from the pH 2 suspensions after isothermal sintering. (C) 2003 Elsevier Ltd and Techna S.r.l. All rights reserved.
    關聯: CERAMICS INTERNATIONAL Volume: 29 Issue: 7 Pages: 821-828
    显示于类别:[化學工程與材料工程學系暨碩士班] 期刊論文

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