Solid-Liquid Equilibria for Six Binary Mixtures of Nonanedioic Acids, Decanedioic Acid, 3-Methylheptanedioic Acid, 2,2-Dimethylbutanedioic Acid, and 2,3-Dimethylbutanedioic Acid

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题名:	Solid-Liquid Equilibria for Six Binary Mixtures of Nonanedioic Acids, Decanedioic Acid, 3-Methylheptanedioic Acid, 2,2-Dimethylbutanedioic Acid, and 2,3-Dimethylbutanedioic Acid
作者:	Wang, Tzu-Chi Chan, Chi-Yang
贡献者:	化材系
关键词:	PENTANEDIOIC ACID HEPTANEDIOIC ACID HEXANEDIOIC ACID BENZOIC-ACID PREDICTION DSC
日期:	2014-11
上传时间:	2015-01-19 15:04:12 (UTC+8)
摘要:	Solid-liquid equilibria of dicarboxylic acids for binary mixtures-nonanedioic acid (1) + 3-methylheptanedioic acid (2) (eutectic temperature T-E = 342.25 K, eutectic composition x(1E) = 0.364); nonanedioic acid (1) + 2,2-dimethylbutanedioic acid (2) (T-E = 367.51 K, x(1E) = 0.653); nonanedioic acid (1) + 2,3-dimethylbutanedioic acid (2) (T-E = 354.27 K, x(1E) = 0.463); decanedioic acid (1) + 3-methylheptanedioic acid (2) (T-E = 352.47 K, x(1E) = 0.134); decanedioic acid (1) + 2,2-dimethylbutanedioic acid (2) (T-E = 384.38 K, x(1E) = 0.483); and decanedioic acid (1) + 2,3-dimethylbutanedioic acid (2) (T-E = 365.38 K, x(1E) = 0.192)-are measured using differential scanning calorimetry (DSC) and correlated using the ClarkeGlew equation in this study. Simple eutectic phase diagrams for these systems are observed. The experimental results are correlated using the Wilson and nonrandom two-liquid (NRTL) activity coefficient models, and satisfactory results are presented.
關聯:	JOURNAL OF CHEMICAL AND ENGINEERING DATA Volume: 59 Issue: 11 Pages: 3814-3819
显示于类别:	[化學工程與材料工程學系暨碩士班] 期刊論文

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