本計畫欲建立以氧化石墨烯材料為主的氣相樣品及液相樣品智慧型節能型感測 系統的開發及應用，內容分為兩大系統，第一大系統為節能型及高機械強度的化學感 測元件的開發:將利用新穎性的製膜技術，層接式醯胺共價鍵結製膜技術 (Layer-by-layer and peptide reaction covalently anchored technique)，來開發以氧化石墨烯 材料為基底材料的節能型及高機械強度的氣相樣品及液相樣品之感測元件。此系統將 建立(1):以層接式醯胺共價鍵結製膜技術將氧化石墨烯及其衍生物及石墨烯氧化物複 合材料等為基底材料固結於軟性基板及硬性基板製成室溫型化學感測器之最佳化製膜 條件；(2): 以氧化石墨烯及其衍生物及石墨烯氧化物複合材料等為基底材料設計各種 的不同形式之 transducer sensors 來量測訊號製成如直流電式(電阻型)、交流電式(阻抗 型)、質量變化(頻率改變量式；QCM)及電化學式等氣相樣品及液相樣品之室溫型化學 感測器。第二大系統為節能型及智慧型的氣相樣品及液相感測系統的建立。此系統可 分為(1): 以氧化石墨烯材料為基底材料的節能型及高機械強度的感測陣列(sensor array) 之可攜式氣相感測模組結合主成份分析法的智慧化應用探討；(2): 製備一套串聯式多 流道液相石英晶體微天平感測系統的設計、製作及系統最佳化探討及結合主成份分析 法的智慧化應用探討。 The portable, smart and saving-energy sensing system will be fabricated based on graphene oxide, reduced graphene oxide and their derivatives by layer-by-layer and peptide reaction covalently anchored technique in this study. The smart sensing system was divided into two categories of sensor devices and sensing/module system. For the sensor devices, (1): fabrication of graphene oxide, reduced graphene oxide and their derivatives films on rigid or flexible substrate by layer-by-layer and peptide reaction covalently anchored technique as flexible chemical sensors, quartz crystal microbalance sensors and electrochemical sensors. For the sensing/module system, (1): design, fabrication and application of portable smart gas phase real-time sensing system using principal component analysis; (2) design, fabrication and application of series connection on-line flow-injection smart liquid phase multi-channel quartz crystal microbalance sensing system using principal component analysis will be investigated in this study.
