| 題名: | Properties and preparation of compatibilized nylon 6 nanocomposites/ABS blends: Part II - Physical and thermal properties |
| 作者: | Lai, S.-M.
Li, H.-C.
Liao, Y.-C. |
| 貢獻者: | 化工系 |
| 關鍵詞: | nylon 6 nanocomposite
poly(acrylonitrile-butadiene-styrene)terpolymers (ABS)
metallocene polyethylene grafted maleic anhydride (POE-g-MA)
polybutadiene grafted maleic anhydride (PB-g-MA)
crystallization kinetics |
| 日期: | 2007 |
| 上傳時間: | 2009-11-13 14:09:56 (UTC+8) |
| 摘要: | The physical and thermal properties of nanoclay filled nylon 6 (nano-nylon 6) blended with poly(acrylonitrile-butadiene-styrene)terpolymers (ABS) were investigated using metallocene polyethylene grafted maleic anhydride (POE-gMA) or polybutadiene grafted maleic anhydride (PB-g-MA) as a compatibilizer. Cooling conditions significantly affected the crystalline structure of nano-nylon 6. No clear effect of both compatibilizers on the dispersion of clay has been observed via transmission electron microscope analysis. Through morphology observation, the ABS particle sizes tended to decrease with the addition of compatibilizers, especially in PB-g-MA cases, suggesting a good interfacial bonding between nano-nylon 6 matrix and ABS dispersed phase. Non-isothermal crystallization results indicated that the crystallization temperatures slightly changed with increasing content of compatibilizers. In addition, melting behaviors with different crystal forms varied widely with cooling conditions. The crystallization kinetics under isothermal conditions reflected that introduced compatibilizers impeded the growth rate, especially for PB-g-MA compatibilized system. (C) 2007 Elsevier Ltd. All rights reserved. |
| 關聯: | EUROPEAN POLYMER JOURNAL Volume: 43 Issue: 5 Pages: 1660-1671 |
| 顯示於類別: | [化學工程與材料工程學系暨碩士班] 期刊論文
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