Li4Ti5O12-coated graphite anode materials for lithium-ion batteries

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题名:	Li4Ti5O12-coated graphite anode materials for lithium-ion batteries
作者:	Lee, ML (Lee, Meng-Lun) Li, YH (Li, Yu Han) Liao, SC (Liao, Shih-Chieh) Chen, JM (Chen, Jin-Ming) Yeh, JW (Yeh, Jien-Wei) Shih, HC (Shih, Han C.)
贡献者:	Inst Nanomat, Dept Chem Engn & Mat Engn
关键词:	Lithium-ion battery Graphite Li4Ti5O12 High temperature
日期:	2013-12-01
上传时间:	2014-02-21 13:34:33 (UTC+8)
摘要:	In this study, we synthesized and characterized Li4Ti5O12(LTO)-coated graphite as an anode material for Li-batteries. The surface of graphite powders was uniformly coated by the LTO nanoparticles to form a core-shelled structure via a sol-gel process, followed by calcination. The average size of graphite core was 20 mu m while the thickness of LTO shell was 60 nm to 100 nm. We found that LTO-coated graphite has better rate-capability and cycle life at RT and 55 degrees C, compared with the pristine graphite. The electrochemical impedance spectroscopy (EIS) results of the cell with LTO-coated graphite anode showed a significant suppression of the impedance rise after 60 cycles. In addition, the Raman spectrum showed that after 60 charge-discharge cycles at 55 degrees C, the I-D/I-G ratio of the LTO-coated graphite electrode increased slightly, while that of the pristine graphite electrode increased significantly. The batteries with LTO-coated graphite anode exhibited excellent cyclic ability and high temperature performance. (C) 2013 Elsevier Ltd. All rights reserved.
關聯:	ELECTROCHIMICA ACTA Volume: 112 Pages: 529-534 Published: DEC 1 2013
显示于类别:	[化學工程與材料工程學系暨碩士班] 期刊論文

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