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https://irlib.pccu.edu.tw/handle/987654321/2499
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| 題名: | Enhancing pitting corrosion resistance of AlxCrFe1.5MnNi0.5 high-entropy alloys by anodic treatment in sulfuric acid |
| 作者: | Lee, C. P.
Chen, Y. Y.
Hsu, C. Y.
Yeh, J. W.
Shih, H. C. |
| 貢獻者: | 化材系 |
| 關鍵詞: | High-entropy alloy
Anodic Film
EIS
XPS
Passivity |
| 日期: | 2008 |
| 上傳時間: | 2009-11-03 11:05:36 (UTC+8) |
| 摘要: | High-entropy alloys differ completely from the alloy system is present in between 5 and 35 at.%. The crystal structures and physical properties of high those of conventional alloys. The electrochemical impedance spectra (EIS) of the AlxCrFe1.5MnNi0.5 (x=0, 0.3, 0.5) alloys, obtained in 0.1 M HCl solution, clearly revealed that the corrosion resistance values were determined to increase from 21 to 34 Omega cm(2) as the aluminum content increased from 0 to 0.5 mol, and were markedly lower than that of 304 stainless steel (243 Omega cm(2)). At passive potential, the corresponding current declined with the anodizing time accounting, causing passivity by the growth of the multi-component anodized film in H2SO4 solution. X-ray photoelectron spectroscopy (XPS) analyses revealed that the surface of anodized Al0.3CrFe1.5MnNi0.5 alloy formed aluminum and chromium oxide film which was the main passivating compound on the alloy. This anodic treatment increased the corrosion resistance in the EIS measurements, of the CrFe1.5MnNi0.5 and Al0.3CrFe1.5MnNi0.5 alloys by two orders of magnitude. Accordingly, the anodic treatment of the AlxCrFe1.5MnNi0.5 alloys optimized their surface structures and minimized their susceptibility to pitting corrosion. (C) 2008 Elsevier B.V. All rights reserved. |
| 關聯: | THIN SOLID FILMS Volume: 517 Issue: 3 Pages: 1301-1305 |
| 顯示於類別: | [化學工程與材料工程學系暨碩士班] 期刊論文
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