Mathematical Modeling for the Pultrusion of Polymethyl Methacrylate Based Composites

文化大學機構典藏 CCUR > 理工學院 > 工學院 > 化學工程與材料工程學系暨碩士班 > 期刊論文 > Item 987654321/24283

jsp.display-item.identifier=請使用永久網址來引用或連結此文件: https://irlib.pccu.edu.tw/handle/987654321/24283

题名:	Mathematical Modeling for the Pultrusion of Polymethyl Methacrylate Based Composites
作者:	Chen, CH (Chen, Chin-Hsing)
贡献者:	Dept Chem & Mat Engn
关键词:	pultrusion polymethyl methacrylate fibers differential scanning calorimetry kinetic mathematical model composites
日期:	2012-03
上传时间:	2013-02-22 16:07:58 (UTC+8)
摘要:	The thermokinetic behavior of polymethyl methacrylate (PMMA)-based composites during the pultrusion of glass fiber reinforced composites was investigated using a mathematical model accounting for the heat transfer and heat generation during the reaction. The equations of continuity and energy balance, coupled with a kinetic expression for the reaction system were solved using a finite difference method to calculate the temperature profiles in the thickness direction in a rectangular pultrusion die. A kinetic model, dP/dt = -eta A(o)exp(-E(p)/RT) (2[I](o) - [Z](o)) P(m)(1-P/P(f))(n) (1 - exp ( - k(d)(t - t(z)))), was proposed to describe the reaction behavior of a PMMA resin. Kinetic parameters for the model were found from isothermal differential scanning calorimetry (DSC) scans using a multiple regression technique. The kinetic parameters gA(o) = 1.459 x 10(9) min(-1), E(p) = 10.62 kcal/mol, m = 1.095, and n = 0.893 were obtained. The predictions of the model will be compared with experimental results. It can be found that the theoretical predicted values of temperature profiles along the pultrusion die length were in good agreement with experimental data, which implies that the mathematical model was suitable for the pultrusion processes. (C) 2011 Wiley Periodicals, Inc. J Appl Polym Sci 123: 2228-2233, 2012
關聯:	JOURNAL OF APPLIED POLYMER SCIENCE 卷: 123 期: 4 頁數: 2228-2233
显示于类别:	[化學工程與材料工程學系暨碩士班] 期刊論文

文件中的档案:

档案	描述	大小	格式	浏览次数
index.html		0Kb	HTML	399	检视/开启

检视Licence

在CCUR中所有的数据项都受到原著作权保护.

数据加载中.....