Core-Shelled MCMB-Li4Ti5O12 Anode Material for Lithium-ion Batteries

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Title:	Core-Shelled MCMB-Li4Ti5O12 Anode Material for Lithium-ion Batteries
Authors:	Lee, ML (Lee, Meng-Lun) Liao, SC (Liao, Shih-Chieh) Chen, JM (Chen, Jing-Ming) Yeh, JW (Yeh, Jien-Wei) Shih, HC (Shih, Han C.)
Contributors:	Inst Mat Sci & Nanotechnol
Keywords:	Lithium-ion battery Li4Ti5O12 Graphite MCMB
Date:	2012-10
Issue Date:	2013-02-19 14:29:40 (UTC+8)
Abstract:	In this study, we have synthesized and characterized Li4Ti5O12 (LTO)-coated meso-carbon micro beads (MCMB) as an anode material for Li-batteries. The surface of MCMB powders was uniformly coated by the LTO nanoparticles to form a core-shell structure via a sol-gel process, followed by calcination. The average size of MCMB core was 15 mu m while the thickness of LTO shell was 80 to 120 nm. We found that LTO-coated MCMB had better rate-capability and cycle life, compared with the pristine MCMB. Electro-chemical impedance spectroscopy (EIS) results showed that after 40 cycles, the cell resistance of the LTO-coated MCMB electrode increased slightly, while that of the pristine MCMB electrode increased significantly. The enhanced performance of the LTO-coated MCMB electrode is attributed to the LTO coating, which suppresses the increase in the charge-transfer resistance during prolonged cycle.
Relation:	JOURNAL OF THE CHINESE CHEMICAL SOCIETY 卷: 59 期: 10 頁數: 1206-1210
Appears in Collections:	[Department of Chemical & Materials Engineering] journal articles

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