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https://irlib.pccu.edu.tw/handle/987654321/20961
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| 题名: | Effect of plasma modification of single wall carbon nanotubes on ethanol vapor sensing |
| 作者: | Liu, CK (Liu, Chun-Kuo)
Huang, MW (Huang, Meng-Wen)
Wu, JM (Wu, Jyh-Ming)
Shih, HC (Shih, Han C.) |
| 贡献者: | 化材所 |
| 关键词: | Single wall carbon nanotubes (SWCNTs)
Microwave plasma enhanced chemical vapor deposition (MPECVD)
Surface modification
Resistance
Ethanol
Gas sensor |
| 日期: | 2010-09 |
| 上传时间: | 2011-12-09 15:26:59 (UTC+8) |
| 摘要: | The oxygen and fluorine modified single wall carbon nanotubes (SWCNTs) were manufactured by microwave plasma enhanced chemical vapor deposition (MPECVD), and were developed as novel gas sensor materials. The sensor characteristic has shown a p-type response with resistance enhancement upon exposure to 100 ppm ethanol at room temperature. Oxygen plasma modification can increase the sensor response from 1.13 to 1.74 on process duration of 30 s due to the apparent elimination of amorphous carbon, as demonstrated by FESEM and Raman results. However, oxygen plasma modification has no effective assistance in decreasing the response and recovery time. By applying fluorine plasma modification, the sensor response only increases from 1.13 to 1.51 on process duration of 60s, but the response and recovery time can decrease apparently from 178 to 54 s and 364 to 97 s due to the existence of numerous fluorine-included functional groups, as demonstrated by XPS and AES results. Therefore, the plasma modified SWCNT can elevate the sensitivity and reactivity for room temperature ethanol sensing. (C) 2010 Elsevier B.V. All rights reserved. |
| 显示于类别: | [化學工程與材料工程學系暨碩士班] 期刊論文
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