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    請使用永久網址來引用或連結此文件: https://irlib.pccu.edu.tw/handle/987654321/20227


    題名: TiXFeCoNi 合金氧化物薄膜光導性之研究
    作者: 范馨壬
    貢獻者: 材料科學與奈米科技研究所
    關鍵詞: 氧化物薄膜
    光電導性
    日期: 2010
    上傳時間: 2011-11-07 13:24:34 (UTC+8)
    摘要: 本論文是以Ti、Fe、Co、Ni四種元素依照等莫耳比例配製成TiXFeCoNi合金靶材,其中的x=0、0.25、0.5、0.75和1,以高真空直流濺鍍機濺鍍其合金薄膜,再將合金薄膜進行真空高溫退火熱處理,放置於真空高溫爐中1000℃-30分鐘,以產生低電阻之TiXFeCoNi合金氧化物薄膜。本論文在探討初鍍薄膜及氧化物薄膜之微結構與電性等性質,再將這些氧化物薄膜置於天然陽光及紫外燈(UVA、UVB及UVC)下進行光激發實驗,觀察其電阻變化情形。
    薄膜性質分析包括使用場發射掃瞄式電子顯微鏡(FE-SEM)作微結構觀察,同時利用四點探針法量測電阻率。
    在本論文最重要的結果發現是TiXFeCoNi氧化合金薄膜的電阻率會受到天然太陽光影響,陽光越強薄膜的電阻率就降低越快,陽光光線的強弱會影響電阻率的升降,另外,發現紫外線(UVA、UVB)的照射都不是造成薄膜其電阻率下降的原因。而紫外線 UVA 則有短暫的降低電阻係數效應。其原因應是紫外線燈的波長不夠小,或是紫外線燈的功率不夠大所致。

    Four elements of Ti, Fe, Co and Ni were selected to produce
    TiXFeCoNi (x=0、0.25、0.5、0.75 and 1) alloy target in this study. The thin
    films were produced by the vacuum DC sputtering technique. Then, the
    TiXFeCoNi thin films were vacuum annealed at 1000°C for 30 min, and
    these thin films became to metal oxide films because the air still leaked
    into the vacuum furnace during annealing. This thesis investigated the
    microstructures and electric properties of as-deposited and as-annealed
    TiXFeCoNi thin films. Also, placing these oxide films under the sunlight
    and ultraviolet (UVA、UVB、UVC) to observe their photoconductivity.
    The microstructures of the TiXFeCoNi thin films were analyzed by
    field-emission scanning electron microscope (FE-SEM). Their
    resistivities were measured by four-point probe method.
    In this paper, the most importation result is the resistivity of the
    TiXFeCoNi oxide thin films could be significantly decreased by sunlight.
    In addition, ultraviolet (UVA and UVB) did not influence the resistivity
    of these oxide thin films; but the ultraviolet UVA had some effect to
    decrease the resistivity of the TiFeCoNi oxide film.
    顯示於類別:[化學工程與材料工程學系暨碩士班] 博碩士論文

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