Halide Functionality Dependent Formation of Molecular Receptors and Their Ion Recognition Properties

CCUR > College of Natural Science and Engineering > College of Science > Department of Chemistry & Graduate Institute of Applied Chemistry > journal articles > Item 987654321/17373

Please use this identifier to cite or link to this item: https://irlib.pccu.edu.tw/handle/987654321/17373

Title:	Halide Functionality Dependent Formation of Molecular Receptors and Their Ion Recognition Properties
Authors:	蔡啟堂;孫世勝;陳柏宇
Contributors:	化學系
Date:	2009-05
Issue Date:	2010-10-28 10:38:57 (UTC+8)
Abstract:	The halide functionality on N-bridged tripodal receptors has shown a distinct behavior on their self-assembly structures and binding ability toward HgCl2 and ClO4− anions. The receptors containing fluoro, chloro, and iodo groups crystallized to form hemicarcerands in the solid state, whereas the receptor with a bromo group forms a molecular capsule via C−H···Br and C−H···π interactions. The cavity of the molecular capsule is tunable and is capable of reversible encapsulating-releasing the guest molecules by pH modulation.
Relation:	Organic Letters Vol. 11(9) P.1867-1870
Appears in Collections:	[Department of Chemistry & Graduate Institute of Applied Chemistry ] journal articles

Files in This Item:

File	Description	Size	Format
index.html		0Kb	HTML	568	View/Open