H-Bonded effects on supramolecular liquid crystalline trimers containing photoluminescent cores

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題名:	H-Bonded effects on supramolecular liquid crystalline trimers containing photoluminescent cores
作者:	蔡啟堂;H.Lin, H.Sheu;C.Chang
貢獻者:	化學系
日期:	2001-12
上傳時間:	2010-10-28 10:18:35 (UTC+8)
摘要:	Several series of hydrogen-bonded (H-bonded) liquid crystalline trimers are constructed by complexation of two complementary components containing various bifunctional photoluminescent (PL) acceptor cores and monofunctional proton donors (in a 1∶2 molar ratio). These supramolecular liquid crystalline trimers (i.e. H-bonded trimers 1/3, 1/4, 1/5, 1/6, 2/3, 2/4, 2/5 and 2/6) are, respectively, obtained from bifunctional bis-pyridyl acceptors (containing conjugated benzene and thiophene centers) (1 and 2) complexed with monofunctional carboxylic acids (containing benzene, thiophene or naphthalene) (3–6) in a 1∶2 acceptor–donor group stoichiometry. Though the PL bis-pyridyl acceptors (1 and 2) do not possess any mesophases, the distinct mesomorphism and supramolecular architecture of these H-bonded trimers are confirmed by polarizing optical microscopy (POM), DSC, and powder X-ray diffraction (XRD) experiments. Moreover, the PL properties of the photoluminescent bis-pyridyl cores can be adjusted not only by the central structures of the cores but also by their surrounding non-photoluminescent proton donors. In general, redder shifts occur in PL spectra of H-bonded trimers when proton donors of smaller pKa values are H-bonded to the photoluminescent cores. Significantly, different wavelengths and polarized light of PL emission can be obtained in these supramolecular structures possessing both liquid crstalline and photoluminescent properties
關聯:	Journal of Materials Chemistry 2001, n.11, 2958-2965
顯示於類別:	[化學系所] 期刊論文

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